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Monitoring NO2 Production of a Diesel Oxidation Catalyst

2012-01-24
A combination of laboratory reactor measurements and vehicle FTP testing has been combined to demonstrate a method for diagnosing the formation of NO2 from a diesel oxidation catalyst (DOC). Using small cores from a production DOC and simulated diesel exhaust, the laboratory reactor experiments are used to support a model for DOC chemical reaction kinetics. The model we propose shows that the ability to produce NO2 is chemically linked to the ability of the catalyst to oxidize hydrocarbon (HC). For thermally damaged DOCs, loss of the HC oxidation function is simultaneous with loss of the NO2 production function. Since HC oxidation is the source of heat generated in the DOC under regeneration conditions, we conclude that a diagnostic of the DOC exotherm is able to detect the failure of the DOC to produce NO2. Vehicle emissions data from a 6.6 L Duramax HD pick-up with DOC of various levels of thermal degradation is provided to support the diagnostic concept.
Video

Updated SAE Standards (J2012, J1979, J1930, J1699)

2012-01-24
Revisions to the California OBD-II diesel regulations required many updates to various SAE and ISO on-board diagnostic standards; these include major revisions to SAE J1979, J1699-3, J2012 and J1930. This presentation is intended to review the background for these changes as well as the revisions made in these documents. Presenter Robert Gruszczynski, Volkswagen of America
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OBD Approval Process

2012-01-24
The OBD approval process can be a frustrating time for both manufacturer and ARB staff. For manufacturers, a long approval process can sometimes mean accepting deficiencies prematurely in exchange for an approval. For ARB staff, they are inundated with highly technical information which they must review, garner understanding of and then apply their experience to evaluate it for compliance. OBD approval anxiety can be minimized, if not avoided, when manufacturers understand ARB�s expectations. This presentation will take you through some unwritten rules and common pitfalls which can impede the approval process, thus providing a guideline to a less painful and more efficient certification document review and approval. Presenter Mark Frank, Winterpark Engineering Llc
Video

Transesterification of Waste Cooking Oil in Presence of Crushed Seashell as a Support for Solid Heterogeneous Catalyst

2011-12-05
Developing relatively cheap and widely available resources for heterogeneous solid catalyst synthesis is a promising approach for biodiesel fuel industry. Seashell which is essentially calcium carbonate can be used as a basic support for transesterification heterogeneous catalysts. In the present investigation, the alcoholysis of waste frying oil has been carried out using seashell-supported K3 PO4 as solid catalyst. Presenter Essam Oun Al-Zaini, PhD student, UNSW
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